7. The dependence of chain scission and racemization on temperature results from molecular motion, "cage effect" and steric hindrance during recombination.
分子量降低和消旋作用对温度的依赖性,是由于分子运动和笼罩效应以及重合的空间位阻效应所致。
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8. The rate constant of racemization of L-Pro increased with decreasing acidity of the carboxylic acid. However, the racemization of L-His was most rapid in acetic acid.
消旋速率因羧酸溶剂的不同而异:L-组氨酸在乙酸溶剂中消旋最快,而L-脯氨酸在正丁酸溶剂中最快。
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9. By the way, if you're curious about why racemization is so much less accurate a clock than C-14 for dating a tooth's age, part of the explanation has to do with temperature.
10. However, when the researchers applied both techniques to teeth, they realized that the racemization offered an additional useful detail, a good gauge of an individual's age at death.
11. By analyzing how much racemization of its aspartic acid occurred, scientists can determine how old the tooth's owner was at death - generally accurate to about 5.5 years, plus or minus 4.2 years.
12. By analyzing how much racemization of its aspartic acid occurred, scientists can determine how old the tooth's owner was at death - generally accurate to about 5.5 years, plus or minus 4.2 years.